BBC titles available under the deal include Doctor Who, Life On Mars, Spooks, and Planet Earth.
The deal with ITV allows Amazon to offer a range of shows including Above Suspicion, Prime Suspect, Inspector Morse, Cold Feet and Secret Diary of a Call Girl.
Lovefilm CEO Simon Calver said: “We are thrilled to be bringing together great British TV content with Europe’s leading film subscription service.
“This gives LOVEFiLM an even more powerful, unique offering of instant programming for our members to view across a growing number of platforms, for one low monthly price.”
Customers can access Lovefim’s streaming service PCs, Sony’s PlayStation 3, Apple’s iPad, web-enabled TV sets and Blu-ray players and Microsoft’s Xbox 360.